A new rhombohedral modification of EuNi5In.
Identifieur interne : 001628 ( Main/Exploration ); précédent : 001627; suivant : 001629A new rhombohedral modification of EuNi5In.
Auteurs : RBID : pubmed:21727613Abstract
A rhombohedral modification of europium pentanickel indide, r-EuNi(5)In, crystallizes in the R ̅3m space group and adopts the UCu(5)In structure type. The structure is closely related to the hexagonal, h-EuNi(5)In, form (CeNi(5)Sn type). Both EuNi(5)In modifications are composed of CaCu(5) (EuNi(5))-, MgCu(2) (InNi(2))- and NiAs (EuNi)-type slabs in a 1:2:1 ratio. The atoms in the structure have high coordination numbers, viz. 20 and 18 for europium, 14 for indium, and 12 and 10 for nickel. The structure features a two-dimensional network of (2)(∞)[Ni(8)] tetrahedral clusters arranged in the ab plane.
DOI: 10.1107/S0108270111022359
PubMed: 21727613
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">A new rhombohedral modification of EuNi5In.</title><author><name sortKey="Bigun, Inna" uniqKey="Bigun I">Inna Bigun</name><affiliation wicri:level="1"><nlm:affiliation>Department of Analytical Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodia Str. 6, 79005 Lviv, Ukraine.</nlm:affiliation><country xml:lang="fr">Ukraine</country><wicri:regionArea>Department of Analytical Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodia Str. 6, 79005 Lviv</wicri:regionArea></affiliation></author><author><name sortKey="Smetana, Volodymyr" uniqKey="Smetana V">Volodymyr Smetana</name></author><author><name sortKey="Kalychak, Yaroslav" uniqKey="Kalychak Y">Yaroslav Kalychak</name></author></titleStmt><publicationStmt><date when="2011">2011</date><idno type="doi">10.1107/S0108270111022359</idno><idno type="RBID">pubmed:21727613</idno><idno type="pmid">21727613</idno><idno type="wicri:Area/Main/Corpus">001291</idno><idno type="wicri:Area/Main/Curation">001291</idno><idno type="wicri:Area/Main/Exploration">001628</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A rhombohedral modification of europium pentanickel indide, r-EuNi(5)In, crystallizes in the R ̅3m space group and adopts the UCu(5)In structure type. The structure is closely related to the hexagonal, h-EuNi(5)In, form (CeNi(5)Sn type). Both EuNi(5)In modifications are composed of CaCu(5) (EuNi(5))-, MgCu(2) (InNi(2))- and NiAs (EuNi)-type slabs in a 1:2:1 ratio. The atoms in the structure have high coordination numbers, viz. 20 and 18 for europium, 14 for indium, and 12 and 10 for nickel. The structure features a two-dimensional network of (2)(∞)[Ni(8)] tetrahedral clusters arranged in the ab plane.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">21727613</PMID><DateCreated><Year>2011</Year><Month>07</Month><Day>05</Day></DateCreated><DateCompleted><Year>2011</Year><Month>10</Month><Day>24</Day></DateCompleted><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1600-5759</ISSN><JournalIssue CitedMedium="Internet"><Volume>67</Volume><Issue>Pt 7</Issue><PubDate><Year>2011</Year><Month>Jul</Month></PubDate></JournalIssue><Title>Acta crystallographica. Section C, Crystal structure communications</Title><ISOAbbreviation>Acta Crystallogr C</ISOAbbreviation></Journal><ArticleTitle>A new rhombohedral modification of EuNi5In.</ArticleTitle><Pagination><MedlinePgn>i42-4</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S0108270111022359</ELocationID><Abstract><AbstractText>A rhombohedral modification of europium pentanickel indide, r-EuNi(5)In, crystallizes in the R ̅3m space group and adopts the UCu(5)In structure type. The structure is closely related to the hexagonal, h-EuNi(5)In, form (CeNi(5)Sn type). Both EuNi(5)In modifications are composed of CaCu(5) (EuNi(5))-, MgCu(2) (InNi(2))- and NiAs (EuNi)-type slabs in a 1:2:1 ratio. The atoms in the structure have high coordination numbers, viz. 20 and 18 for europium, 14 for indium, and 12 and 10 for nickel. The structure features a two-dimensional network of (2)(∞)[Ni(8)] tetrahedral clusters arranged in the ab plane.</AbstractText><CopyrightInformation>© 2011 International Union of Crystallography</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Bigun</LastName><ForeName>Inna</ForeName><Initials>I</Initials><Affiliation>Department of Analytical Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodia Str. 6, 79005 Lviv, Ukraine.</Affiliation></Author><Author ValidYN="Y"><LastName>Smetana</LastName><ForeName>Volodymyr</ForeName><Initials>V</Initials></Author><Author ValidYN="Y"><LastName>Kalychak</LastName><ForeName>Yaroslav</ForeName><Initials>Y</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2011</Year><Month>06</Month><Day>23</Day></ArticleDate></Article><MedlineJournalInfo><Country>Denmark</Country><MedlineTA>Acta Crystallogr C</MedlineTA><NlmUniqueID>8305826</NlmUniqueID><ISSNLinking>0108-2701</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2011</Year><Month>4</Month><Day>22</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2011</Year><Month>6</Month><Day>09</Day></PubMedPubDate><PubMedPubDate PubStatus="epublish"><Year>2011</Year><Month>6</Month><Day>23</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2011</Year><Month>7</Month><Day>6</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2011</Year><Month>7</Month><Day>6</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2011</Year><Month>7</Month><Day>6</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pii">S0108270111022359</ArticleId><ArticleId IdType="doi">10.1107/S0108270111022359</ArticleId><ArticleId IdType="pubmed">21727613</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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